Geoffrey I , Count of Angouleme
Geoffrey I , Count was born about 1014.  He died in 1048.

 Petronille d'Archiac
Petronille was born about 1000.  She died after 1048.

 Humberge de Angouleme
Humberge was born in 0978.  She died after 1068.

 Fulk , Count of Angouleme
He died about 1089.