Edward Ward must have been involved in the settlement of San Bernerdino, CA; Daughter Barbara Alice was born in Utah 1860 but daugher Madora Ward was born in CA in 1863 and Luella Ward was born in 1867 in CA.
He was married to both Elizabeth Parker and Ann Leather at the same time.
I can find no record of his immigration to the USA. He was born in England in 1833 and was married in USA in 1855, thus he immigrated during that time period. It does not appear that his father George Ward immigrated as he was born and died in England.
His mother was Isabella Ward and I have no idea of how his parents were related.